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ऐसे पदार्थ जिनमे सामान्य अवस्था में मुक्त इलेक्ट्रोन नही होते लेकिन विशेष परिस्थितियों जैसे उच्च ताप या अशुद्धि मिलाने पर मुक्त इलेक्ट्रोन प्राप्त किये जा सकते है कहलाते है
1) सुचालक पदार्थ
2) कुचालक पदार्थ
3) अचालक पदार्थ
4) अर्ध्द्चालक पदार्थ
4) अर्ध्द्चालक पदार्थ